Počet záznamů: 1
Monodisperse magnetic composite poly(glycidyl methacrylate)/La0.75Sr0.25MnO3 microspheres by the dispersion polymerization
0343957 - UMCH-V 2011 RIV GB eng J - Článek v odborném periodiku
Horák, Daniel - Trchová, Miroslava - Beneš, Milan J. - Veverka, Miroslav - Pollert, Emil
Monodisperse magnetic composite poly(glycidyl methacrylate)/La0.75Sr0.25MnO3 microspheres by the dispersion polymerization.
Polymer. Roč. 51, č. 14 (2010), s. 3116-3112 ISSN 0032-3861
Grant CEP: GA AV ČR KAN200200651; GA ČR GA203/09/0857; GA MŠk 2B06053
Výzkumný záměr: CEZ:AV0Z40500505; CEZ:AV0Z10100521
Klíčová slova: magnetic * dispersion polymerization * glycidyl methacrylate
Kód oboru RIV: CD - Makromolekulární chemie
Impakt faktor: 3.829, rok: 2010
Monodisperse magnetic poly(glycidyl methacrylate) microspheres were prepared by dispersion polymerization of glycidyl methacrylate in cyclohexane in the presence of La0.75Sr0.25MnO3 nanoparticles, surface of which was modified with penta(propylene glycol) methacrylate phosphate (PPGMAP). However, only agglomerates were formed by the dispersion polymerization in toluene. Sterical stabilizer was poly(styrene-block-hydrogenated butadiene-block-styrene) and initiators investigated were 2,2′-azobisisobutyronitrile (AIBN) and 4,4′-azobis(4-cyanovaleric acid) (ACVA). Effects of initiators and other reaction conditions on properties of the composite microspheres were evaluated. The phase composition of the magnetic polymer composite microspheres and the size of magnetic cores were determined by X-ray powder diffraction. The characterization was completed by magnetization measurements, atomic absorption spectroscopy, TEM, SEM and ATR FTIR spectroscopy.
Trvalý link: http://hdl.handle.net/11104/0005930