Počet záznamů: 1  

Monodisperse magnetic composite poly(glycidyl methacrylate)/La0.75Sr0.25MnO3 microspheres by the dispersion polymerization

  1. 1.
    0343957 - ÚMCH 2011 RIV GB eng J - Článek v odborném periodiku
    Horák, Daniel - Trchová, Miroslava - Beneš, Milan J. - Veverka, Miroslav - Pollert, Emil
    Monodisperse magnetic composite poly(glycidyl methacrylate)/La0.75Sr0.25MnO3 microspheres by the dispersion polymerization.
    Polymer. Roč. 51, č. 14 (2010), s. 3116-3112. ISSN 0032-3861. E-ISSN 1873-2291
    Grant CEP: GA AV ČR KAN200200651; GA ČR GA203/09/0857; GA MŠMT 2B06053
    Výzkumný záměr: CEZ:AV0Z40500505; CEZ:AV0Z10100521
    Klíčová slova: magnetic * dispersion polymerization * glycidyl methacrylate
    Kód oboru RIV: CD - Makromolekulární chemie
    Impakt faktor: 3.829, rok: 2010

    Monodisperse magnetic poly(glycidyl methacrylate) microspheres were prepared by dispersion polymerization of glycidyl methacrylate in cyclohexane in the presence of La0.75Sr0.25MnO3 nanoparticles, surface of which was modified with penta(propylene glycol) methacrylate phosphate (PPGMAP). However, only agglomerates were formed by the dispersion polymerization in toluene. Sterical stabilizer was poly(styrene-block-hydrogenated butadiene-block-styrene) and initiators investigated were 2,2′-azobisisobutyronitrile (AIBN) and 4,4′-azobis(4-cyanovaleric acid) (ACVA). Effects of initiators and other reaction conditions on properties of the composite microspheres were evaluated. The phase composition of the magnetic polymer composite microspheres and the size of magnetic cores were determined by X-ray powder diffraction. The characterization was completed by magnetization measurements, atomic absorption spectroscopy, TEM, SEM and ATR FTIR spectroscopy.
    Trvalý link: http://hdl.handle.net/11104/0005930

     
     
Počet záznamů: 1  

  Tyto stránky využívají soubory cookies, které usnadňují jejich prohlížení. Další informace o tom jak používáme cookies.