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Study of Asymmetric Stereoselective Hydrogenation in Presence of Ionic Liquid in Microfluidic Chip Reactor.

  1. 1.
    0475758 - ÚCHP 2018 SK eng C - Konferenční příspěvek (zahraniční konf.)
    Vychodilová, Hana - Stavárek, Petr - Hejda, Stanislav - Pěnkavová, Věra - Bendová, Magdalena - Vlček, Dalibor - Klusoň, Petr
    Study of Asymmetric Stereoselective Hydrogenation in Presence of Ionic Liquid in Microfluidic Chip Reactor.
    Proceedings. Bratislava: Slovak Society of Chemical Engineering, 2017 - (Blahušiak, M.; Mihal, M.), s. 739. ISBN 978-80-89597-58-1.
    [International Conference of SSCHE /44./. Demänovská dolina (SK), 22.05.2017-26.05.2017]
    Grant CEP: GA ČR GA15-04790S
    Institucionální podpora: RVO:67985858
    Klíčová slova: microfluidic chip reactor * stereoselective hydrogenation * ionic liquid
    Kód oboru RIV: CI - Průmyslová chemie a chemické inženýrství
    Obor OECD: Chemical process engineering

    In recent years, there have been several successful attempts of microreactor application to production of specialty chemicals [1,2] mainly for pharma and other related industry fields. In this study, we focused on the application of microfluidic chip reactor to the stereoselective hydrogenation of methylacetoacetate (MAA) to isomeric (R)-(+) or (S)-(-)-methyl-3-hydroxybutanoates over a chiral ([RuCl((R)-BINAP)(p-cymene)]Cl) complex [3] immobilized in the mixed [N8222][Tf2N]/methanol/water solvent phase, and performed inside of a microfluidic chip reactor. A presence of ionic liquid (quarternary ammonium salts) allows for an easy separation of this catalyst via its pseudo-immobilization.
    Trvalý link: http://hdl.handle.net/11104/0272389
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