Počet záznamů: 1  

Thermal stability of perovskite phase in heavily Mn-doped SrTiO3 nanoparticles in oxidizing and reducing atmospheres

  1. 1. 0470445 - FZU-D 2017 RIV US eng J - Článek v odborném periodiku
    Makarova, Marina - Artemenko, Anna - Kopeček, Jaromír - Laufek, František - Zemenová, Petra - Trepakov, Vladimír - Dejneka, Alexandr
    Thermal stability of perovskite phase in heavily Mn-doped SrTiO3 nanoparticles in oxidizing and reducing atmospheres.
    Scripta Materialia. Roč. 116, Apr (2016), s. 21-25 ISSN 1359-6462
    Grant CEP: GA ČR(CZ) GBP108/12/G108; GA TA ČR TA03010743; GA MŠk LO1409; GA MŠk LM2015088
    Institucionální podpora: RVO:68378271
    Klíčová slova: surface segregation * perovskite * nanocrystalline microstructure * thermally activated processes * metastable phases
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 3.747, rok: 2016

    Complex investigations of the thermal stability as well as Mn-dopant distribution depending on chemical composition and processing condition have been performed in heavily doped SrTi1-xMnxO3 nanoparticles with x = 0.2 and 0.4. Prepared nanopowders reveal stable enough cubic perovskite structure even after treatment in oxidizing atmosphere up to 1000 °C. At the same time treatment in reducing atmosphere leads to decrease of the Mn solubility limit. Mn distribution evidences a weak tendency of Mn ions to migrate to surface. This migration increases in air and decreases at treatment in oxygen atmosphere.
    Trvalý link: http://hdl.handle.net/11104/0268083