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Ruthenium (II) Complexes with 6,7-Diaza[5]phenacene.

  1. 1.
    0468158 - UCHP-M 2017 CZ eng C - Konferenční příspěvek (zahraniční konf.)
    Beránek, Tomáš - Žádný, Jaroslav - Jakubík, Pavel - Církva, Vladimír - Storch, Jan
    Ruthenium (II) Complexes with 6,7-Diaza[5]phenacene.
    Book of Abstracts. 2016, s. 65. ISBN N.
    [Advances in Organic, Bioorganic and Pharmaceutical Chemistry Liblice 2016 /51./. Lázně Bělohrad (CZ), 11.11.2016-13.11.2016]
    Grant CEP: GA TA ČR TA01010646
    Institucionální podpora: RVO:67985858
    Klíčová slova: ruthenium cpmplexes * electronic proprties * photocatalysis
    Kód oboru RIV: CC - Organická chemie

    In this work we focused on preparation of novel bidentate and fully aromatic N,N-ligand and its ruthenium complexes. 6,7-Diaza[5]phenacene (1) was synthetized from 4-bromoisoquinoline by microwave-assisted tandem Hyama-Heck cross coupling reaction3 followed by photocyclization (Scheme 1). With 6,7-diaza[5]phenacene (1) in our hand, we prepared some new ruthenium(II) complexes (e.g. 2) , characterized them from structural point of view and determined some of their electronic and optical properties with regard to their application potential.
    Trvalý link: http://hdl.handle.net/11104/0266016
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