Počet záznamů: 1  

Frustrated Lewis pairs-assisted reduction of carbonyl compounds

  1. 1. 0443293 - UOCHB-X 2016 RIV GB eng J - Článek v odborném periodiku
    Marek, Aleš - Pedersen, M. H. F.
    Frustrated Lewis pairs-assisted reduction of carbonyl compounds.
    Tetrahedron. Roč. 71, č. 6 (2015), s. 917-921 ISSN 0040-4020
    Institucionální podpora: RVO:61388963
    Klíčová slova: frustrated Lewis pairs * hydrogen activation * benzyl alcohol * tritium labeling * labeled compounds
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 2.645, rok: 2015

    An alternative and robust method for the reduction of carbonyl groups by frustrated Lewis pairs (FLPs) is reported in this paper. With its very mild reaction conditions, good to excellent yields, absolute regioselectivity and the non-metallic character of the reagent, it provides an excellent tool for H-1, H-2 as well as H-3 chemistry. It is a new strategy for the one-pot synthesis of aromatic alcohols selectively labeled with heavy isotopes of hydrogen.
    Trvalý link: http://hdl.handle.net/11104/0246072