Počet záznamů: 1
Oxidative Photoredox-Catalytic Activation of Aliphatic Nucleophiles for C(sp3)-C(sp2) Cross-Coupling Reactions
- 1.0437258 - ÚOCHB 2015 RIV DE eng J - Článek v odborném periodiku
Jahn, Emanuela - Jahn, Ullrich
Oxidative Photoredox-Catalytic Activation of Aliphatic Nucleophiles for C(sp3)-C(sp2) Cross-Coupling Reactions.
Angewandte Chemie - International Edition. Roč. 53, č. 49 (2014), s. 13326-13328. ISSN 1433-7851. E-ISSN 1521-3773
Institucionální podpora: RVO:61388963
Klíčová slova: amino acids * cross-coupling * nickel * persistent radical effect * photoredox catalysis
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 11.261, rok: 2014
In the light you will find the road (Led Zeppelin): Visible-light photoredox catalysis leads the way in overcoming the reactivity limitations of alkyl nucleophiles in cross-coupling reactions. Iridium-triggered oxidative photoredox activation of alkyltrifluoroborate or carboxylic acids affords alkyl radicals, which undergo nickel-catalyzed cross-coupling reactions.
Trvalý link: http://hdl.handle.net/11104/0240797
Počet záznamů: 1