Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin

0435070 - ÚFCH JH 2015 RIV GB eng J - Článek v odborném periodiku
Kolivoška, Viliam - Mohos, M. - Pobelov, I. V. - Rohrbach, S. - Yoshida, K. - Hong, W. - Fu, Y. C. - Moreno-Garcia, P. - Mészáros, G. - Broekmann, P. - Hromadová, Magdaléna - Sokolová, Romana - Valášek, M. - Wandlowski, T.
Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin.
Chemical Communications. Roč. 50, č. 79 (2014), s. 11757-11759. ISSN 1359-7345. E-ISSN 1364-548X
Grant CEP: GA ČR(CZ) GA14-05180S
Institucionální podpora: RVO:61388955
Klíčová slova: electrochemistry * spectroscopy * beta-cyclodextrin
Kód oboru RIV: CG - Elektrochemie
Impakt faktor: 6.834, rok: 2014

The forces required for the detachment of ferrocene (Fc) from beta-cyclodextrin (beta CD) in a single host (beta CD)-guest (Fc) complex were investigated using force spectroscopy under electrochemical conditions. The redox state of the guest Fc moiety as well as the structure of the supporting matrix was found to decisively affect the nanomechanical properties of the complex.
Trvalý link: http://hdl.handle.net/11104/0238989