Počet záznamů: 1  

Bis[N-(3-aminopropyl)propane-1,3-diamine- κ.sup.3./sup.N,N´,N´´]cadmium nitrate perchlorate

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    0383991 - FZÚ 2013 RIV DK eng J - Článek v odborném periodiku
    Goudarziafshar, H. - Nikoorazm, M. - Abbasityula, Y. - Eigner, Václav - Dušek, Michal
    Bis[N-(3-aminopropyl)propane-1,3-diamine- κ3N,N´,N´´]cadmium nitrate perchlorate.
    Acta Crystallographica Section E-Structure Reports Online. Roč. 68, Part 3 (2012), "m273"-"sup10". ISSN 1600-5368. E-ISSN 2056-9890
    Grant ostatní: AV ČR(CZ) AP0701
    Program: Akademická prémie - Praemium Academiae
    Výzkumný záměr: CEZ:AV0Z10100521
    Klíčová slova: crystal structure * X-ray diffraction * Jana2006 * disorder in main residue
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 0.347, rok: 2011

    The title complex, [Cd(C6H17N3) SUB>2](ClO4)(NO3), was synthesized by the reaction of Cd(NO3)2.4H2O, bis(3- minopropyl)- amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd2+ cation, two tridentate bis(3-aminopropyl)amine ligands, one nitrate anion and one perchlorate anion. The Cd2+ cation is coordinated by six N atoms of the bis(3-aminopropyl)amine ligands in a slightly distorted octahedral coordination geometry. In the crystal, molecules are held together by an intricate network of N-H...O interactions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10).
    Trvalý link: http://hdl.handle.net/11104/0213765

     
     
Počet záznamů: 1  

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