0383991 - FZÚ 2013 RIV DK eng J - Článek v odborném periodiku
Goudarziafshar, H. - Nikoorazm, M. - Abbasityula, Y. - Eigner, Václav - Dušek, Michal
Bis[N-(3-aminopropyl)propane-1,3-diamine- κ³N,N´,N´´]cadmium nitrate perchlorate.
Acta Crystallographica Section E-Structure Reports Online. Roč. 68, Part 3 (2012), "m273"-"sup10". ISSN 1600-5368. E-ISSN 2056-9890
Grant ostatní: AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Výzkumný záměr: CEZ:AV0Z10100521
Klíčová slova: crystal structure * X-ray diffraction * Jana2006 * disorder in main residue
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 0.347, rok: 2011 ; AIS: 0.035, rok: 2011
DOI: https://doi.org/10.1107/S1600536812004400

The title complex, [Cd(C6H17N3) SUB>2](ClO4)(NO3), was synthesized by the reaction of Cd(NO3)2.4H2O, bis(3- minopropyl)- amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd2+ cation, two tridentate bis(3-aminopropyl)amine ligands, one nitrate anion and one perchlorate anion. The Cd2+ cation is coordinated by six N atoms of the bis(3-aminopropyl)amine ligands in a slightly distorted octahedral coordination geometry. In the crystal, molecules are held together by an intricate network of N-H...O interactions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802 (3):0.198 (3), similarly to the nitrate anion, with a ratio of 0.762 (10):0.238 (10).
Trvalý link: http://hdl.handle.net/11104/0213765