0383798 - ÚOCHB 2013 RIV NL eng J - Článek v odborném periodiku
Levee, L. - Calogero, C. - Barbieri, E. - Byrne, S. - Donahue, C. - Eisenberg, M. - Hattenbach, S. - Le, J. - Capitani, J. F. - Roithová, J. - Schröder, Detlef
Formation of argon-boron bonds in the reactions of BFn+/2+ cations with neutral argon.
International Journal of Mass Spectrometry. Roč. 323, 1 Jun (2012), s. 2-7. ISSN 1387-3806. E-ISSN 1873-2798
Grant CEP: GA ČR GA203/09/1223
Grant ostatní: European Research Council(XE) AdG HORIZOMS
Institucionální podpora: RVO:61388963
Klíčová slova: argon compound * boron fluoride * dication * gas phase reactivity * mass spectrometry * neon compound
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 2.142, rok: 2012 ; AIS: 0.665, rok: 2012
DOI: https://doi.org/10.1016/j.ijms.2012.05.006

Experimental data on the reactions of argon with BFn+ monocations (n = 0-3) and BFn2+ dications (n = 1, 2) and dications reveal the formation of the new argon species ArBF2+ and ArBF2+. Theoretical calculations on the stability of these ions using density functional theory confirm the formation of the rare-gas compounds, but their formation is only exothermic for the reaction Ar + BF22+ -> ArBF2+ + F. According to theory, the corresponding neon compounds all involve endothermic pathways and could hence only be formed via involvement of excited states.
Trvalý link: http://hdl.handle.net/11104/0213632