0181779 - UFCH-W 20030219 RIV NL eng J - Článek v odborném periodiku
Hazafy, D. - Sobocíková, M. - Štěpnička, P. - Ludvík, Jiří - Kotora, M.
Selective Mono- and di {(perfluoroalkyl)acylation} of Ferrocene.
Journal of Fluorine Chemistry. Roč. 124, č. 1 (2003), s. 177-181. ISSN 0022-1139. E-ISSN 1873-3328
Grant CEP: GA AV ČR IAA4072203
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: perfluoroalkylation * perfluoroacylation * ferrocene
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 1.193, rok: 2003

The selective synthesis of mono- and 1.1'-di {perfluoroalkyl)acylated ferrocenes by Friedel-Crafts acylation with (perfluoroalkyl)acyl halides is described. The acyl derivatives were further converted to the corresponding ferrocenes by reduction of the carbonyl group with LiAlH4/AlCl3. Electrochemical studies of all the obtained substituted ferrocenes were carried out to assess the influence of the perfluoroalkyl ponytails on their redox behavior.
Trvalý link: http://hdl.handle.net/11104/0078298