0181384 - UFCH-W 20020048 RIV DK eng J - Journal Article
Mach, Karel - Kubišta, Jiří - Císařová, I. - Štěpnička, P.
[.mu.-1.kappa.2 O,O´:2(.eta.5)-Cyclopentadienyl-carboxylato][2(.eta.5)-diphenylphosphinocyclopentadienyl]Bis[1,1(.eta.5)-tetramethylcyclopentadienyl]Iron(II)-Titanium(III).
Acta Crystallographica Section C-Crystal Structure Communications. Roč. 58, - (2002), s. 116-118. ISSN 0108-2701. E-ISSN 2053-2296
R&D Projects: GA ČR GP203/01/P002; GA ČR GA203/99/0846
Institutional research plan: CEZ:AV0Z4040901
Keywords : titanium * ferrocene * carboxylato complex
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 0.659, year: 2002

Reacting stoichiometric amounts of 1-(diphenylphosphino)-ferrocenecarboxylic acid and [Ti(.eta.5-C5HMe4)2(.eta.2-Me3SiC=CSiMe3)] produced the title carboxylatotitanocene complex. The angle subtended by the Ti/O/O' plane, where O and O' are the donor atoms of the .kappa.2-carboxylate group, and the plane of the carboxyl-substituted ferrocene cyclopentadienyl is 24.93(6)°.
Permanent Link: http://hdl.handle.net/11104/0077965