Počet záznamů: 1
Synthesis of C.sub.2./sub.-Symmetrical [1,1'-Binaphthalene]-2,2'-Diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis
- 1.0181269 - UFCH-W 20010187 RIV CZ eng J - Článek v odborném periodiku
Vyskočil, Š. - Meca, L. - Kubišta, Jiří - Maloň, Petr - Kočovský, P.
Synthesis of C2-Symmetrical [1,1'-Binaphthalene]-2,2'-Diamines with Additional Chelating Groups Attached to the Nitrogen Atoms as Potential Ligands for Asymmetric Catalysis.
Collection of Czechoslovak Chemical Communications. Roč. 65, - (2000), s. 539-548. ISSN 0010-0765
Grant CEP: GA ČR GA203/98/1185
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: biaryls * binaphthyls * amine reductive alkylation
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 0.960, rok: 2000
Reductive amination of 2-hydroxybenzaldehyde using a combination of NaBH4 and (R)-[1,1'-binaphthalene]-2,2'-diamine, served as the key step in the synthesis of the potentially tetradentate ligands (R)-N,N'-bis(2-hydroxybenzyl)[1,1'-binaphthalene]-2,2'-diamine and (R)-N,N'-bis(2-hydroxybenzyl)-N,N'-dimethyl[1,1'-binaphthalene]-2,2'-diamine. CD spectra of the new binaphthyl derivatives are presented.
Trvalý link: http://hdl.handle.net/11104/0077852
Počet záznamů: 1