Počet záznamů: 1
A Time-Resolved Infrared Spectroscopic Study of [M(SnR.sub.3./sub.).sub.2./sub.(CO).sub.2./sub.-(ŕ-diimine)] (M=Ru, Os; R=Ph, Me): Evidence of Charge Redistribution in the Lowest-Excited State
- 1.0181257 - UFCH-W 20010173 RIV GB eng J - Článek v odborném periodiku
Weinstein, J. A. - Slageren van, J. - Stufkens, D. J. - Záliš, Stanislav - George, M. W.
A Time-Resolved Infrared Spectroscopic Study of [M(SnR3)2(CO)2-(ŕ-diimine)] (M=Ru, Os; R=Ph, Me): Evidence of Charge Redistribution in the Lowest-Excited State.
Journal of the Chemical Society - Dalton Transactions. č. 18 (2001), s. 2587-2592. ISSN 0300-9246
Grant CEP: GA MŠMT OC D14.20; GA MŠMT OC D15.10
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: transition metal diimine complexes * time-resolved infrared spectroscopy * electronic structures
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 2.310, rok: 1999
Nanosecond time-resolved step-scan IR (s2-TRIR) spectra are reported which indicate that the initial SBLCT excitation is followed by a redistribution of the electron density if this transition has an appreciable charge transfer character. TD DFT calculations confirm this character.
Trvalý link: http://hdl.handle.net/11104/0077840
Počet záznamů: 1