0162198 - UIACH-O 200013 RIV US eng J - Článek v odborném periodiku
Jeon, Y. P. - Roth, Michal - Kwon, Y. J.
Infinite-dilution partial molar properties of naphthalene and biphenyl in carbon dioxide from supercritical fluid chromatography: composition effects in the stationary phase.
Journal of Physical Chemistry A. Roč. 104, č. 55 (2000), s. 5396-5400. ISSN 1089-5639. E-ISSN 1520-5215
Grant CEP: GA ČR GA203/98/0635
Kód oboru RIV: CE - Biochemie
Impakt faktor: 2.754, rok: 2000

The temperature and pressure effects on retention of naphthalene and biphenyl in supercritical fluid chromatography were investigated within 35-70 oC and 7.5-15 MPa. The retention factors were used to derive the infinite-dilution partial molar volumes of the two solutes in supercritical carbon dioxide, the infinite/dilution molar volumes of the two solutes in supercritical carbon dioxide, the infinite- dilution molar enthalpies of transfer of the two solutes from the stationary phase to supercritical CO2, and some quantities measuring short-range interactions between CO2 and the solutes.
Trvalý link: http://hdl.handle.net/11104/0001194