Počet záznamů: 1

High-frequency dielectric spectroscopy of BaTiO3 core - silica shell nanocomposites: problem of interdiffusion

  1. 1.
    0368156 - FZU-D 2012 RIV SG eng J - Článek v odborném periodiku
    Nuzhnyy, Dmitry - Petzelt, Jan - Bovtun, Viktor - Kempa, Martin - Savinov, Maxim - Elissalde, C. - Chung, U.-C. - Michau, D. - Estournes, C. - Maglione, M.
    High-frequency dielectric spectroscopy of BaTiO3 core - silica shell nanocomposites: problem of interdiffusion.
    Journal of Advanced Dielectrics. Roč. 1, č. 3 (2011), 309-317 ISSN 2010-135X
    Grant CEP: GA ČR GA202/09/0430
    Výzkumný záměr: CEZ:AV0Z10100520
    Klíčová slova: core-shell nanocomposites * infrared and THz spectroscopy * barium titanate * effective medium approximation
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus

    Three types of BaTiO3 core - amorphous nanoshell composite ceramics were processed from the same core-shell powder by standard sintering, spark-plasma sintering and two-step sintering techniques and characterized by XRD, HRSEM and broadband dielectric spectroscopy in the frequency range 103-1013 Hz including the THz and IR range. The samples differed by porosity and by the amount of interdiffusion from the cores to shells, in correlation with their increasing porosity. The dielectric spectra were also calculated using suitable models based on effective medium approximation. The measurements revealed a strong dielectric dispersion below the THz range, which cannot be explained by the modeling, and whose strength was in correlation with the degree of interdiffusion. It is assigned to an effect of the interdiffusion layers, giving rise to a strong interfacial polarization.
    Trvalý link: http://hdl.handle.net/11104/0202583