Počet záznamů: 1

Synthesis and structural studies of a new class of quaternary ammonium salts, which are derivatives of cage adamanzane type aminal 1,3,6,8-tetraazatricyclo [4.3.1.1.sup.3,8./sup.]undecane (TATU)

  1. 1.
    0365631 - FZU-D 2012 RIV GB eng J - Článek v odborném periodiku
    Rivera, A. - Sadat-Bernal, J. - Ríos-Motta, J. - Dušek, Michal - Palatinus, Lukáš
    Synthesis and structural studies of a new class of quaternary ammonium salts, which are derivatives of cage adamanzane type aminal 1,3,6,8-tetraazatricyclo [4.3.1.13,8]undecane (TATU).
    Chemistry Central Journal. Roč. 5, č. 55 (2011), 55/1-55/8 ISSN 1752-153X
    Grant ostatní: AVČR(CZ) Praemium Academiae
    Výzkumný záměr: CEZ:AV0Z10100521
    Klíčová slova: quaternary ammonium salts * adamanzane * X-ray diffraction
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 3.281, rok: 2011

    Novel mono N-alkyl quaternary ammonium salts (3a-f) were prepared using the Menschutkin reaction. The structures of these new salts were established using various spectral and electrospray ionization mass spectrometry (ESI-MS) analyses. Compound (3b) was also analyzed using X-ray crystallography. It was noted that alkyl chain length did not significantly affect the reaction because all employed alkyl iodide electrophiles reacted in a similar fashion with the aminal 1.
    Trvalý link: http://hdl.handle.net/11104/0200825