Počet záznamů: 1

Direct observation of triple ions in aqueous solutions of nickel(II) sulfate: A Molecular link between gas phase and bulk behavior

  1. 1.
    0363851 - UOCHB-X 2012 RIV US eng J - Článek v odborném periodiku
    Schröder, Detlef - Ducháčková, L. - Tarábek, Ján - Karwowska, M. - Fijalkowski, K. J. - Ončák, Milan - Slavíček, Petr
    Direct observation of triple ions in aqueous solutions of nickel(II) sulfate: A Molecular link between gas phase and bulk behavior.
    Journal of the American Chemical Society. Roč. 133, č. 8 (2011), s. 2444-2451 ISSN 0002-7863
    Grant CEP: GA ČR GA203/08/1487; GA MŠk LC512; GA AV ČR KAN400400651
    Grant ostatní: European Research Council(XE) AdG HORIZOMS
    Výzkumný záměr: CEZ:AV0Z40550506; CEZ:AV0Z40400503
    Klíčová slova: electrospray ionization * infrared spectroscopy * mass spectrometry * microhydration * nickel sulfate
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 9.907, rok: 2011

    Electrospray ionization of aqueous nickel(II) sulfate provides direct experimental evidence for the formation of triple ions of the type [Ni2(SO4)(H2O)n]2+ and [Ni(SO4)2]2-, whose existence in aqueous solution has previously been proposed based on relaxation spectroscopy.
    Trvalý link: http://hdl.handle.net/11104/0199494