Počet záznamů: 1

Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase

  1. 1.
    0363624 - UOCHB-X 2012 RIV US eng J - Článek v odborném periodiku
    Ducháčková, L. - Schröder, Detlef - Roithová, J.
    Effect of the Carboxylate Shift on the Reactivity of Zinc Complexes in the Gas Phase.
    Inorganic Chemistry. Roč. 50, č. 7 (2011), s. 3153-3158 ISSN 0020-1669
    Grant CEP: GA ČR GA203/08/1487
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: acetate * infrared multiphoton dissociation * mass spectrometry * zinc
    Kód oboru RIV: CA - Anorganická chemie
    Impakt faktor: 4.601, rok: 2011

    The effect of different modes of the carboxylato ligands on the reactivity of gaseous zinc-acetate complexes is investigated by infrared multiphoton dissociation spectroscopy. In [(Imi)nZn(CH3COO)]+ complexes (Imi = imidazole, n = 1-3) the coordination changes from bi- to monodentate upon coordination of the third imidazole ligand ("carboxylate shift").
    Trvalý link: http://hdl.handle.net/11104/0006535