Počet záznamů: 1

Perhaloalkylation of Metal Enolates—Unconventional and Versatile

  1. 1.
    0361368 - UOCHB-X 2012 RIV DE eng J - Článek v odborném periodiku
    Amatov, Tynchtyk - Jahn, Ullrich
    Perhaloalkylation of Metal Enolates—Unconventional and Versatile.
    Angewandte Chemie - International Edition. Roč. 50, č. 20 (2011), s. 4542-4544 ISSN 1433-7851
    Grant CEP: GA ČR GA203/09/1936
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: electron transfer * enols * perhaloalkylation * radical reactions * valence tautomerism
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 13.455, rok: 2011

    Radically unconventional: Natural products with di- and trichloromethyl groups and trifluoromethylated pharmaceuticals and agrochemicials are interesting compounds, often with intriguing properties. These types of compounds can be prepared by the direct perhaloalkylation of carbonyl compounds in which enolate reactivity and radical reactivity are merged.
    Trvalý link: http://hdl.handle.net/11104/0198692