Počet záznamů: 1

Hydration modes of an amphiphilic molecule 2: NMR, FTIR and theoretical study of the interactions in the system water–1,2-dimethoxyethane

  1. 1.
    0359963 - UMCH-V 2012 RIV NL eng J - Článek v odborném periodiku
    Kříž, Jaroslav - Dybal, Jiří
    Hydration modes of an amphiphilic molecule 2: NMR, FTIR and theoretical study of the interactions in the system water–1,2-dimethoxyethane.
    Chemical Physics. Roč. 382, 1-3 (2011), s. 104-112 ISSN 0301-0104
    Grant CEP: GA ČR GA203/09/1478; GA ČR GAP205/11/1657
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: hydrophobic hydration * dimethoxyethane * NMR
    Kód oboru RIV: CD - Makromolekulární chemie
    Impakt faktor: 1.896, rok: 2011

    Using 1H and 13C NMR spectra, PFG diffusion measurements and relaxations as well as FTIR spectra and DFT quantum-mechanical calculations, it was shown that the dimethoxyethane molecule becomes wrapped at higher water contents in a cooperative hydration envelope utilizing both H-O...H and C-H...O hydrogen bonds.
    Trvalý link: http://hdl.handle.net/11104/0197632