Počet záznamů: 1

Suspension polymerization of aniline hydrochloride in non-aqueous media

  1. 1.
    0359118 - UMCH-V 2012 RIV GB eng J - Článek v odborném periodiku
    Konyushenko, Elena - Stejskal, Jaroslav - Trchová, Miroslava - Prokeš, J.
    Suspension polymerization of aniline hydrochloride in non-aqueous media.
    Polymer International. Roč. 60, č. 5 (2011), s. 794-797 ISSN 0959-8103
    Grant CEP: GA AV ČR IAA400500905; GA AV ČR IAA100500902
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: conducting polymer * polyaniline * non-aqueous media
    Kód oboru RIV: CD - Makromolekulární chemie
    Impakt faktor: 1.902, rok: 2011

    The oxidation of aniline hydrochloride by ammonium peroxydisulfate in non-aqueous media was studied, when themonomer or oxidant or both were not completely soluble. Polyaniline was formed in acetone, methanol and toluene. Aniline oligomers only were produced in chloroform and n-butylacetate. No interaction of the monomer and the oxidant was observed in dimethylsulfoxide and N-methylpyrrolidone. UV-visible and Fourier transform infrared spectra were recorded in order to study themolecular structure of the final products. Conductivity was measured for conducting protonated forms and corresponding bases. An explanation of aniline hydrochloride oxidation in various organicmedia is offered.
    Trvalý link: http://hdl.handle.net/11104/0006426