Počet záznamů: 1

Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion

  1. 1.
    0357559 - UACH-T 2011 RIV CZ eng J - Článek v odborném periodiku
    Carr, MJ. - Clegg, W. - Kennedy, J.D. - Londesborough, Michael Geoffrey Stephen - Kilner, C. A.
    Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion.
    Collection of Czechoslovak Chemical Communications. Roč. 75, č. 8 (2010), s. 807-812 ISSN 0010-0765
    Výzkumný záměr: CEZ:AV0Z40320502
    Klíčová slova: borane cluster * thiaborane * macropolyhedral
    Kód oboru RIV: CA - Anorganická chemie
    Impakt faktor: 0.853, rok: 2010

    The novel eighteen-vertex macropolyhedral dithiaborane anion [S2B16H17](-) 1 has been obtained as its [tmndH](+) salt from the reaction of [S2B17H17] 2 and tmnd in solution in the presence of [RhCl2(eta(5)-C5Me5)](2). It has two cluster skeletal electrons more than the three previously reported eighteen-vertex dithiaborane {S2B16} species n-[S2B16H16], n-[S2B16H15](-) and iso-[S2B16H16], and the anion consists structurally of an arachno {SB9} and a nido {B-9} cluster unit fused with two boron atoms in common, and with an endo-to-exo sulfur bridge that also links the two subclusters together.
    Trvalý link: http://hdl.handle.net/11104/0195808