Počet záznamů: 1

A combined extraction and DFT study on the complexation of the silver cation with dibenzo-18-crown-6

  1. 1.
    0356376 - UMCH-V 2011 RIV AT eng J - Článek v odborném periodiku
    Makrlík, E. - Toman, Petr - Vaňura, P.
    A combined extraction and DFT study on the complexation of the silver cation with dibenzo-18-crown-6.
    Monatshefte fur Chemie. Roč. 142, č. 2 (2011), s. 137-140 ISSN 0026-9247
    Grant CEP: GA ČR(CZ) GAP205/10/2280
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: crown ethers * macrocycles * complexation
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 1.532, rok: 2011

    Extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements were used to determine the stability constant of the dibenzo-18-crown-6 • Ag+ complex species in nitrobenzene saturated with water. Furthermore, the structure of the resulting complex was derived by means of theoretical calculations at the density functional level.
    Trvalý link: http://hdl.handle.net/11104/0006336