Počet záznamů: 1

The effect of the pH on the oxidative polymerization of aniline and the morphology and properties of the products

  1. 1.
    0355746 - UMCH-V 2011 RIV RU eng J - Článek v odborném periodiku
    Sapurina, I. Yu. - Stejskal, Jaroslav
    The effect of the pH on the oxidative polymerization of aniline and the morphology and properties of the products.
    Russian Chemical Reviews. Roč. 79, č. 12 (2010), s. 1123-1143 ISSN 0036-021X
    Grant CEP: GA MŠk ME 847
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: polyaniline * conducting polymer * nanotubes
    Kód oboru RIV: CD - Makromolekulární chemie
    Impakt faktor: 2.346, rok: 2010

    The synthesis and properties of the most popular and widely used electrically conducting polymer, polyaniline, are considered. The proposed mechanisms of the molecular synthesis and self-assembly of macromolecules occurring during the polymerization agree with the large body of experimental data. The acidity of the reaction medium is demonstrated to affect the mechanism on aniline oxidative polymerization and the formation of various types of supramolecular structures, namely nanoglobules, nanofibres, nanotubes and microspheres.
    Trvalý link: http://hdl.handle.net/11104/0006313