Počet záznamů: 1

High-Band-Gap Polycrystalline Monolayers of a 12-Vertex p-Carborane on Au(111)

  1. 1.
    0352048 - UOCHB-X 2011 RIV US eng J - Článek v odborném periodiku
    Wrochem von, F. - Scholz, F. - Gao, D. - Nothofer, H. G. - Yasuda, A. - Wessels, J. M. - Roy, S. - Chen, X. - Michl, Josef
    High-Band-Gap Polycrystalline Monolayers of a 12-Vertex p-Carborane on Au(111).
    Journal of Physical Chemistry Letters. Roč. 1, č. 24 (2010), s. 3471-3477 ISSN 1948-7185
    Grant ostatní:NSF(US) CHE-0848477
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: molecular structure * quantum chemistry * general theory
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie

    We have observed that p-carboranes tethered to gold by thiolate linkers form polycrystalline monolayers which are incommensurate with the Au(111) substrate. The incommensurability results from the strong interactions between adjacent p-carborane cages (1.6 eV/molecule) and from the adlayer lattice spacing, which is defined by the cage diameter.
    Trvalý link: http://hdl.handle.net/11104/0191650