Počet záznamů: 1

T-Shaped Molecular Building Blocks by Combined Bridgehead and Bridge Substitution on Bicyclo[1.1.1]pentanes

  1. 1.
    0351981 - UOCHB-X 2011 RIV US eng J - Článek v odborném periodiku
    Kaleta, J. - Michl, Josef - Mazal, C.
    T-Shaped Molecular Building Blocks by Combined Bridgehead and Bridge Substitution on Bicyclo[1.1.1]pentanes.
    Journal of Organic Chemistry. Roč. 75, č. 7 (2010), s. 2350-2356 ISSN 0022-3263
    Grant CEP: GA MŠk ME09114
    Grant ostatní: NSF(US) CHE0848477; NSF(US) OISE-0532040
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: staffanes * molecular electronics
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 4.002, rok: 2010

    Derivatives of bicyclo[1.1.1]pentane differentially substituted in bridgehead (1,3) and bridge (2,4) positions have been synthesized. They represent a new T-shaped structural module consisting of a rigid rod with a nearly freely rotating side arm, possibly useful as a molecular building block in syntheses of more complex covalent or supramolecular scaffolds useful in bottom-up construction of molecular level devices or materials.
    Trvalý link: http://hdl.handle.net/11104/0191600