Počet záznamů: 1

A combined experimental and theoretical study on the complexation of the ammonium cation with valinomycin

  1. 1.
    0349803 - UMCH-V 2011 RIV AT eng J - Článek v odborném periodiku
    Makrlík, E. - Dybal, Jiří - Vaňura, P.
    A combined experimental and theoretical study on the complexation of the ammonium cation with valinomycin.
    Monatshefte fur Chemie. Roč. 141, č. 11 (2010), s. 1191-1194 ISSN 0026-9247
    Grant CEP: GA AV ČR 1ET400500402
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: antibiotics * macrocycles * stability constant
    Kód oboru RIV: CD - Makromolekulární chemie
    Impakt faktor: 1.356, rok: 2010

    From extraction experiments in the two-phase water/nitrobenzene system and gamma-activity measurements, the stability constant of the valinomycin-ammonium complex in nitrobenzene saturated with water was determined. Further, the structure of the resulting complex was derived by means of density functional theory (DFT) calculations.
    Trvalý link: http://hdl.handle.net/11104/0006112