Počet záznamů: 1

The autoprotonation in reduction mechanism of pesticide ioxynil

  1. 1.
    0348590 - UFCH-W 2011 RIV GB eng J - Článek v odborném periodiku
    Sokolová, Romana - Hromadová, Magdaléna - Ludvík, Jiří - Pospíšil, Lubomír - Giannarelli, S.
    The autoprotonation in reduction mechanism of pesticide ioxynil.
    Electrochimica acta. Roč. 55, č. 27 (2010), s. 8336-8340 ISSN 0013-4686
    Grant CEP: GA ČR GA203/09/1607; GA ČR GA203/08/1157; GA MŠk LC510; GA MŠk OC 140
    Výzkumný záměr: CEZ:AV0Z40400503
    Klíčová slova: autoprotonation * organic halides * polarography
    Kód oboru RIV: CG - Elektrochemie
    Impakt faktor: 3.642, rok: 2010

    The reduction mechanism of ioxynil (3,5-diiodo-4-hydroxy-benzonitrile) was studied in dimethylsulfoxide using the electrochemical methods (tast polarography, cyclic voltammetry and controlled potential electrolysis) combined with GC/MS identification of products. The reduction is accompanied by the cleavage of iodide yielding 3-iodo-4-hydroxybenzonitrile. Surprisingly, this process requires only one electron for the exhaustive electrolysis of the starting compound. We showed that the apparent one electron reduction observed in the aprotic solvent is due to the autoprotonation by another molecule of ioxynil. The overall one electron reduction (uptake of two electrons per two molecules of ioxynil) is changed in the presence of a strong proton donor to a two electron process per one molecule.
    Trvalý link: http://hdl.handle.net/11104/0189093