Počet záznamů: 1

Straightforward Synthesis of Substituted p-Quinones: Isolation of a Key Intermediate and Use as a Bridging Ligand in a Diruthenium Complex

  1. 1.
    0345814 - UFCH-W 2011 RIV DE eng J - Článek v odborném periodiku
    Das, H. S. - Weisser, F. - Schweinfurth, D. - Su, Ch. Y. - Bogani, C. - Fiedler, Jan - Sarkar, B.
    Straightforward Synthesis of Substituted p-Quinones: Isolation of a Key Intermediate and Use as a Bridging Ligand in a Diruthenium Complex.
    Chemistry - A European Journal. Roč. 16, č. 10 (2010), s. 2977-2981 ISSN 0947-6539
    Grant CEP: GA MŠk OC 140; GA MŠk OC09043
    Výzkumný záměr: CEZ:AV0Z40400503
    Klíčová slova: cyclic voltammetry * quinones * ruthenium
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 5.476, rok: 2010

    A new transamination method is reported for the synthesis of diamino-substituted p-quinones (see scheme). Asymmetrically substituted p-quinones are shown to be key intermediates in this reaction. The redox properties of these ligands are discussed and their utility in coordination and redox chemistry is shown with a representative example.
    Trvalý link: http://hdl.handle.net/11104/0187001