Počet záznamů: 1

Self-assembled polyaniline nanotubes and nanoribbons/titanium dioxide nanocomposites

  1. 1.
    0345183 - UMCH-V 2011 RIV CH eng J - Článek v odborném periodiku
    Radoičic, M. - Šaponjic, Z. - Nedeljkovic, J. - Ciric-Marjanovic, G. - Stejskal, Jaroslav
    Self-assembled polyaniline nanotubes and nanoribbons/titanium dioxide nanocomposites.
    Synthetic Metals. Roč. 160, 11-12 (2010), s. 1325-1334 ISSN 0379-6779
    Grant CEP: GA ČR GA202/09/1626
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: nanocomposites * nanoribbons * nanostructures
    Kód oboru RIV: JI - Kompozitní materiály
    Impakt faktor: 1.871, rok: 2010

    Self-assembled polyaniline (PANI) nanotubes, accompanied with nanoribbons, were synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in an aqueous medium, in the presence of colloidal titanium dioxide (TiO2) nanoparticles of 4.5 nm size, without added acid. The morphology, structure, and physicochemical properties of the PANI/TiO2 nanocomposites, prepared at various initial aniline/TiO2 mole ratios, were studied by scanning (SEM) and transmission (TEM) electron microscopies, FTIR, Raman and inductively coupled plasma optical emission (ICP-OES) spectroscopies, elemental analysis, X-ray powder diffraction (XRPD), conductivity measurements, and thermogravimetric analysis (TGA). The electrical conductivity of PANI/TiO2 nanocomposites increases in the range 3.8 × 10−4 to 1.1 × 10−3 S cm−1 by increasing aniline/TiO2 mole ratio from 1 to 10.
    Trvalý link: http://hdl.handle.net/11104/0005945