Počet záznamů: 1

Probability distribution function of the polymer end-to-end molecule vector after retraction and its application to step deformation

  1. 1.
    0343541 - UH-J 2011 RIV DE eng J - Článek v odborném periodiku
    Kharlamov, Alexander - Rolón-Garrido, V. H. - Filip, Petr
    Probability distribution function of the polymer end-to-end molecule vector after retraction and its application to step deformation.
    Macromolecular Theory and Simulations. Roč. 19, č. 4 (2010), s. 190-194 ISSN 1022-1344
    Grant CEP: GA ČR GA103/09/2066
    Výzkumný záměr: CEZ:AV0Z20600510
    Klíčová slova: polymer chains * molecular modeling * shear * stress
    Kód oboru RIV: BK - Mechanika tekutin
    Impakt faktor: 1.440, rok: 2010

    The classical Doi-Edwards model describes the dynamics of polymer strands between entanglements and predicts stress in linear polymers. This contribution considers the dynamics of whole molecules within the same tube picture. The probability distribution function of the end-to-end molecule vectors after deformation and retraction was calculated. The second moment of the distribution function coincides with that derived earlier by Doi and Edwards. The damping function shows considerably weaker thinning if the molecule end-to-end vector is considered as a Hookean spring. The present model describes one of the possible mechanisms leading to weaker damping exhibiting, e.g., by branched polymers.
    Trvalý link: http://hdl.handle.net/11104/0185994
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