Počet záznamů: 1

Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

  1. 1.
    0342760 - UFCH-W 2011 RIV GB eng J - Článek v odborném periodiku
    Su, B. - Hatay, I. - Ge, P. Y. - Méndez, M. A. - Corminboeuf, C. - Samec, Zdeněk - Ersöz, M. - Girault, H. H.
    Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media.
    Chemical Communications. Roč. 46, č. 17 (2010), s. 2918-2919 ISSN 1359-7345
    Grant CEP: GA ČR(CZ) GA203/07/1257; GA MŠk OC 177
    Výzkumný záměr: CEZ:AV0Z40400503
    Klíčová slova: ferrocene derivatives * liquid interface * perchloric acid
    Kód oboru RIV: CG - Elektrochemie
    Impakt faktor: 5.787, rok: 2010

    Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH(+), as an active intermediate species, producing hydrogen peroxide and hydrogen in aerobic and anaerobic conditions, respectively.
    Trvalý link: http://hdl.handle.net/11104/0185399