Počet záznamů: 1

A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F]

  1. 1.
    0341016 - UIACH-O 2010 RIV NL eng J - Článek v odborném periodiku
    Beran, Martin - Příhoda, J. - Taraba, J.
    A new route to the syntheses of N-(fluorosulfuryl)sulfonamide salts: Crystal structure of Ph4P+ [CF3SO2NSO2F].
    Polyhedron. Roč. 29, č. 3 (2010), s. 991-994 ISSN 0277-5387
    Výzkumný záměr: CEZ:AV0Z40310501
    Klíčová slova: N-(fluorosulfuryl) sulfonamides * N-(fluorosulfuryl)trifluoromethane sulfonamide * N-(chlorosulfuryl)trifluoromethane
    Kód oboru RIV: CB - Analytická chemie, separace
    Impakt faktor: 2.033, rok: 2010

    A new route for the preparation of potassium and tetraphenylphosphonium salts of N-(fluorosulfuryl)trifluoromethane sulfonamide is described. N-(chlorosulfuryl)-trifluoromethane sulfonamide CF3SO2–NH– SO2Cl, that was used for preparations of both salts, was prepared by the reaction of trifluoromethane sulfonamide CF3SO2NH2 and chlorosulfonic acid in the presence of SOCl2.
    Trvalý link: http://hdl.handle.net/11104/0184131