Počet záznamů: 1

Isotope-sensitive Degenerate [1.3]-Hydrogen Migration versus Competitive Enol-Keto Tautomerization

  1. 1.
    0334353 - UOCHB-X 2010 RIV DE eng J - Článek v odborném periodiku
    Zhang, X. - Zummack, W. - Schröder, Detlef - Weinhold, F. A. - Schwarz, H.
    Isotope-sensitive Degenerate [1.3]-Hydrogen Migration versus Competitive Enol-Keto Tautomerization.
    Chemistry - A European Journal. Roč. 15, č. 44 (2009), s. 11815-11819 ISSN 0947-6539
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: reaction mechanism * hydrogen migration * non-ergodic behavior * keto-enol tautomerism * isotope effects
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 5.382, rok: 2009

    A careful re-investigation of the acetone cation-radical not only provides additional mechanistic insight, but reveals a degenerate 1,3-H migration as a completely novel facet.
    Trvalý link: http://hdl.handle.net/11104/0179112