Počet záznamů: 1

Correlation between catalytic activity and metal cation coordination: NO decomposition over Cu/zeolites

  1. 1.
    0333516 - UOCHB-X 2011 RIV DE eng J - Článek v odborném periodiku
    Pulido, Maria Angeles - Nachtigall, P.
    Correlation between catalytic activity and metal cation coordination: NO decomposition over Cu/zeolites.
    ChemCatChem. Roč. 1, č. 4 (2009), s. 449-453 ISSN 1867-3880
    Grant CEP: GA MŠk LC512
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: deNOx * mechanism * DFT
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie

    The catalytic activity of Cu/zeolites for NO removal depends on the metal cation coordination to the framework. The most active catalysts are those with Cu+ loosely coordinated to the framework. The catalytic cycle is investigated using a periodic DFT model to account for the effect of the zeolite on the stability of reaction intermediates.
    Trvalý link: http://hdl.handle.net/11104/0178477