Počet záznamů: 1

Hydrated metal-oxide versus dihydroxide structures of [MO2H2]+ cations with M=Fe, Co, and Ni

  1. 1.
    0326528 - UOCHB-X 2010 RIV NL eng J - Článek v odborném periodiku
    Schröder, Detlef - Souvi, S. O. - Alikhani, E.
    Hydrated metal-oxide versus dihydroxide structures of [MO2H2]+ cations with M=Fe, Co, and Ni.
    Chemical Physics Letters. Roč. 470, 4/6 (2009), s. 162-165 ISSN 0009-2614
    Grant CEP: GA ČR GA203/08/1487
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: cobalt oxide * electrospray ionization * mass spectrometry * metal nitrates * nickel oxide
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 2.291, rok: 2009

    The formal metal(III) cations [CoO2H2]+ and [NiO2H2]+ are generated by electrospray ionization of aqueous solutions of the corresponding metal(II) nitrates. Experimental and theory predict Fe(OH)2+ to be more stable than (H2O)FeO+, whereas the opposite applies for M = Ni and both isomers are energetically close for M = Co.
    Trvalý link: http://hdl.handle.net/11104/0005272