Crystal structures of the bis-bidentate N.sub.2./sub.S.sub.2./sub. Schiff base ligand and its copper(I) coordination polymer

0521554 - FZÚ 2020 RIV MK eng J - Článek v odborném periodiku
Khalaji, A.D. - Peyghoun, S.J. - Dušek, Michal - Kučeráková, Monika - Eigner, Václav - Akbari, A. - Feizi, N.
Crystal structures of the bis-bidentate N₂S₂ Schiff base ligand and its copper(I) coordination polymer.
Macedonian Journal of Chemistry and Chemical Engineering. Roč. 38, č. 2 (2019), s. 207-214. ISSN 1857-5552. E-ISSN 1857-5625
Grant CEP: GA ČR(CZ) GA18-10438S; GA MŠMT(CZ) LO1603
GRANT EU: European Commission(CZ) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:68378271
Klíčová slova: bis-bidentate ligand * copper(I) coordination polymer * single-crystal * distorted tetrahedral coordination * nano-sized material * crystal structure
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 0.829, rok: 2019
Způsob publikování: Open access

A new flexible bis-bidentate N2S2 Schiff base ligand (2,4-Cl-ba)2dapte = N,Nʹ-bis-(2,4-dichlorobenzaldehyde)-1,2-di(o-iminophenylthio)ethane and its copper(I) coordination polymer [Cu2(μ-I)2(μ-(2,4-Cl-ba)2dapte)]n, were synthesized and characterized by CHN elemental analysis, FT-IR and UV-Vis spectroscopy and single-crystal X-ray diffraction. The coordination geometry around the copper(I) ions is a distorted tetrahedron. Finally, a nano-sized form of the copper(I) coordination polymer [Cu2(μ-I)2(μ-(2,4-Cl-ba)2dapte)]n was prepared by an ultrasonic bath assisted pro-cess and characterized by elemental analysis, FT-IR and SEM.
Trvalý link: http://hdl.handle.net/11104/0306150