Počet záznamů: 1
The Enigma of Methanol Synthesis by Cu/ZnO/Al2O3-Based Catalysts
- 1.
SYSNO ASEP 0585187 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název The Enigma of Methanol Synthesis by Cu/ZnO/Al2O3-Based Catalysts Tvůrce(i) Beck, A. (DE)
Newton, Marc Adrian (UFCH-W)
van de Water, L. G. A. (GB)
van Bokhoven, J. A. (CH)Zdroj.dok. Chemical Reviews. - : American Chemical Society - ISSN 0009-2665
(2024)Poč.str. 136 s. Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova methanol synthesis ; catalysis ; Cu/ZnO/Al2O3 Vědní obor RIV CF - Fyzikální chemie a teoretická chemie Obor OECD Physical chemistry Způsob publikování Omezený přístup Institucionální podpora UFCH-W - RVO:61388955 UT WOS 001195974300001 EID SCOPUS 85189516101 DOI 10.1021/acs.chemrev.3c00148 Anotace The activity and durability of the Cu/ZnO/Al2O3 (CZA) catalyst formulation for methanol synthesis from CO/CO2/H2 feeds far exceed the sum of its individual components. As such, this ternary catalytic system is a prime example of synergy in catalysis, one that has been employed for the large scale commercial production of methanol since its inception in the mid 1960s with precious little alteration to its original formulation. Methanol is a key building block of the chemical industry. It is also an attractive energy storage molecule, which can also be produced from CO2 and H2 alone, making efficient use of sequestered CO2. As such, this somewhat unusual catalyst formulation has an enormous role to play in the modern chemical industry and the world of global economics, to which the correspondingly voluminous and ongoing research, which began in the 1920s, attests. Yet, despite this commercial success, and while research aimed at understanding how this formulation functions has continued throughout the decades, a comprehensive and universally agreed upon understanding of how this material achieves what it does has yet to be realized. After nigh on a century of research into CZA catalysts, the purpose of this Review is to appraise what has been achieved to date, and to show how, and how far, the field has evolved. To do so, this Review evaluates the research regarding this catalyst formulation in a chronological order and critically assesses the validity and novelty of various hypotheses and claims that have been made over the years. Ultimately, the Review attempts to derive a holistic summary of what the current body of literature tells us about the fundamental sources of the synergies at work within the CZA catalyst and, from this, suggest ways in which the field may yet be further advanced. Pracoviště Ústav fyzikální chemie J.Heyrovského Kontakt Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Rok sběru 2025 Elektronická adresa https://pubs.acs.org/doi/10.1021/acs.chemrev.3c00148
Počet záznamů: 1