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Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications
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SYSNO ASEP 0569146 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications Tvůrce(i) Kirakci, Kaplan (UACH-T) SAI, RID, ORCID
Shestopalov, M.A. (RU)
Lang, Kamil (UACH-T) SAI, RID, ORCIDCelkový počet autorů 3 Číslo článku 215048 Zdroj.dok. Coordination Chemistry Reviews. - : Elsevier - ISSN 0010-8545
Roč. 481, APR (2023)Poč.str. 30 s. Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova hexanuclear molybdenum clusters ; core-containing clusters ; biological applications Vědní obor RIV CA - Anorganická chemie Obor OECD Inorganic and nuclear chemistry CEP GC21-16084J GA ČR - Grantová agentura ČR GA21-11688S GA ČR - Grantová agentura ČR Způsob publikování Omezený přístup Institucionální podpora UACH-T - RVO:61388980 UT WOS 000944220900001 EID SCOPUS 85147865538 DOI 10.1016/j.ccr.2023.215048 Anotace The luminescent octahedral molybdenum, tungsten, and rhenium cluster complexes have attracted a broad interest in the past decades for the design of photofunctional materials. These complexes, with the general formula [{M6Li8}La6]n, display red phosphorescence with high quantum yields, quenching of their emission by oxygen, and robust production of singlet oxygen, O2(1Δg). In addition, the wide range of inner (Li) and apical (La) ligands allows for a fine tuning of their physico-chemical, photophysical, and biological properties and for additional functionalization with regards to targeted applications. In this review, we summarize the recent developments towards the use of these complexes for biological applications such as photodynamic therapy, computed tomography, or photoinactivation of bacteria. The synthetic methods and properties of these complexes are presented and we encompass the different approaches towards photo-related biological applications through standalone use of these complexes or by their incorporation into (nano)materials. We identify the key parameters and the challenges for successful biological application of this class of transition metal cluster complexes. Pracoviště Ústav anorganické chemie Kontakt Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Rok sběru 2024 Elektronická adresa https://doi.org/10.1016/j.ccr.2023.215048
Počet záznamů: 1