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Uptake of trace elements and isotope fractionation of Cu and Zn by birch (Betula pendula) growing on mineralized coal waste pile
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SYSNO ASEP 0534809 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Uptake of trace elements and isotope fractionation of Cu and Zn by birch (Betula pendula) growing on mineralized coal waste pile Tvůrce(i) Kříbek, B. (CZ)
Míková, J. (CZ)
Knésl, I. (CZ)
Mihaljevič, M. (CZ)
Sýkorová, Ivana (USMH-B) RID, ORCIDČíslo článku 104741 Zdroj.dok. Applied Geochemistry. - : Elsevier - ISSN 0883-2927
Roč. 122, NOV 2020 (2020)Poč.str. 14 s. Forma vydání Tištěná - P Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova waste rock heap ; self-ignition ; selected trace elements ; soil contamination ; plant contamination Vědní obor RIV DB - Geologie a mineralogie Obor OECD Geology CEP GA15-11674S GA ČR - Grantová agentura ČR Způsob publikování Omezený přístup Institucionální podpora USMH-B - RVO:67985891 UT WOS 000587914200024 EID SCOPUS 85090005619 DOI https://doi.org/10.1016/j.apgeochem.2020.104741 Anotace Aims of the present study were to determine the extent of the uptake of selected trace elements by birch (Betula pendula Roth) growing on the partly burnt coal waste pile and to evaluate isotopic fractionation of copper (Cu) zinc (Zn). Substrates, birch sap and leaves were collected in the coal waste pile and in a reference area outside the waste pile. The concentration of trace elements in birch sap and leaves both in birch growing on the coal waste pile and at reference sites increase in the range of U, As, Se > Cd, Mo, Cu > Pb > Ba ≫ Zn. However, the uptake of elements by birch is restricted when concentration of metals in substrates are too high. Compared to the isotopic composition of Cu in waste substrates and soils (δ65Cu = – 0.93 to + 1.49‰), this element in sap and leaves (δ65Cu = – 0.58 to −1.64 and – 0.59 to – 2.35‰, respectively) is depleted in heavy isotope regardless of plant-available concentration of Cu in substrates. Compared to the isotopic composition of Zn in substrates (δ66Zn = – 0.20 to 1.43‰), its isotopic composition in sap and leaves (δ66Zn = – 0.85 to + 1.00 and – 0.21 to + 0.57‰, respectively) is depleted in the heavy isotope only when the plant-available concentration of Zn in the substrate and soil is high (>20 mg kg−1). At low plant-available concentration of Zn no isotopic fractionation or enrichment of Zn in the heavy isotope was recorded. Pracoviště Ústav struktury a mechaniky hornin Kontakt Iva Švihálková, svihalkova@irsm.cas.cz, Tel.: 266 009 216 Rok sběru 2021 Elektronická adresa https://www.sciencedirect.com/science/article/abs/pii/S088329272030233X?via%3Dihub
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