Počet záznamů: 1

The development of a fully integrated 3D printed electrochemical platform and its application to investigate the chemical reaction between carbon dioxide and hydrazine

SYSNO ASEP	0532030
Druh ASEP	J - Článek v odborném periodiku
Zařazení RIV	J - Článek v odborném periodiku
Poddruh J	Článek ve WOS
Název	The development of a fully integrated 3D printed electrochemical platform and its application to investigate the chemical reaction between carbon dioxide and hydrazine
Tvůrce(i)	Escobar, J. G. (BR) Vaněčková, Eva (UFCH-W)_{SAI, ORCID} Nováková Lachmanová, Štěpánka (UFCH-W)_{ORCID, RID} Vivaldi, F. (IT) Heyda, J. (CZ) Kubišta, Jiří (UFCH-W)_{RID, ORCID} Shestivska, Violetta (UFCH-W)_{RID, ORCID} Španěl, Patrik (UFCH-W)_{RID, ORCID} Schwarzová-Pecková, K. (CZ) Rathouský, Jiří (UFCH-W)_{RID, ORCID} Sebechlebská, Táňa (UFCH-W)_{SAI, ORCID} Kolivoška, Viliam (UFCH-W)_{RID, ORCID}
Číslo článku	136984
Zdroj.dok.	Electrochimica acta. - : Elsevier - ISSN 0013-4686 Roč. 360, NOV 2020 (2020)
Poč.str.	11 s.
Jazyk dok.	eng - angličtina
Země vyd.	GB - Velká Británie
Klíč. slova	3D printing ; Carbon dioxide ; Electrochemical measurements ; Hydrazine ; Numerical simulations
Vědní obor RIV	CF - Fyzikální chemie a teoretická chemie
Obor OECD	Physical chemistry
CEP	GA19-12109S GA ČR - Grantová agentura ČR
	GA18-09848S GA ČR - Grantová agentura ČR
	LM2018124 GA MŠMT - Ministerstvo školství, mládeže a tělovýchovy
Způsob publikování	Omezený přístup
Institucionální podpora	UFCH-W - RVO:61388955
UT WOS	000576817900012
EID SCOPUS	85090003687
DOI	10.1016/j.electacta.2020.136984
Anotace	The combination of computer assisted design and 3D printing has recently enabled fast and inexpensive manufacture of customized ‘reactionware’ for broad range of electrochemical applications. In this work bi-material fused deposition modeling 3D printing is utilized to construct an integrated platform based on a polyamide electrochemical cell and electrodes manufactured from a polylactic acid-carbon nanotube conductive composite. The cell contains separated compartments for the reference and counter electrode and enables reactants to be introduced and inspected under oxygen-free conditions. The developed platform was employed in a study investigating the electrochemical oxidation of aqueous hydrazine coupled to its bulk reaction with carbon dioxide. The analysis of cyclic voltammograms obtained in reaction mixtures with systematically varied composition confirmed that the reaction between hydrazine and carbon dioxide follows 1/1 stoichiometry and the corresponding equilibrium constant amounts to (2.8 ± 0.6) × 103. Experimental characteristics were verified by results of numerical simulations based on the finite-element-method.
Pracoviště	Ústav fyzikální chemie J.Heyrovského
Kontakt	Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
Rok sběru	2021
Elektronická adresa	http://hdl.handle.net/11104/0310632

Počet záznamů: 1