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Direct Decomposition of NO over Co-Mn-Al Mixed Oxides: Effect of Ce and/or K Promoters
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SYSNO ASEP 0531074 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Direct Decomposition of NO over Co-Mn-Al Mixed Oxides: Effect of Ce and/or K Promoters Tvůrce(i) Jirátová, Květa (UCHP-M) RID, ORCID, SAI
Pacultová, K. (CZ)
Karásková, K. (CZ)
Balabánová, Jana (UCHP-M) RID, ORCID, SAI
Koštejn, Martin (UCHP-M) RID, SAI, ORCID
Obalová, L. (CZ)Číslo článku 808 Zdroj.dok. Catalysts. - : MDPI
Roč. 10, č. 7 (2020)Poč.str. 20 s. Jazyk dok. eng - angličtina Země vyd. CH - Švýcarsko Klíč. slova cobalt mixed oxide ; alkali promoter ; nitric oxide Vědní obor RIV CI - Průmyslová chemie a chemické inženýrství Obor OECD Chemical process engineering CEP GA18-19519S GA ČR - Grantová agentura ČR Způsob publikování Open access Institucionální podpora UCHP-M - RVO:67985858 UT WOS 000557246900001 EID SCOPUS 85088289446 DOI 10.3390/catal10070808 Anotace Co-Mn-Al mixed oxides promoted by potassium are known as active catalysts for the direct decomposition of nitric oxide (NO). In this study, the answer to the following question has been considered: does the presence of cerium in K-promoted Co-Mn-Al catalysts substantially affect the physical-chemical properties, activity, and stability in direct NO decomposition? The Co-Mn-Al, Co-Mn-Al-Ce, and Co-Mn-Al-Ce-K mixed oxide catalysts were prepared by the precipitation of corresponding metal nitrates with a solution of Na2CO3/NaOH, followed by the washing of the precipitate and calcination. Two other catalysts were prepared by impregnation of the Ce-containing catalysts with Co and Co+K nitrates. After calcination, the solids were characterized by chemical analysis, XRD, N2 physisorption, FTIR, temperature-programmed reduction, CO2 and O2 desorption (H2-TPR, CO2-TPD, O2-TPD), and X-ray photoelectron spectrometry (XPS). Cerium and especially potassium occurring in the catalysts affected the basicity, reducibility, and surface concentration of active components. Adding cerium itself did not contribute to the increase in catalytic activity, whereas the addition of cerium and potassium did. Catalytic activity in direct NO decomposition depended on combinations of both reducibility and the amount of stronger basic sites determined in the catalysts. Therefore, the increase in cobalt concentration itself in the Co-Mn-Al mixed oxide catalyst does not determine the achievement of high catalytic activity in direct NO decomposition. Pracoviště Ústav chemických procesů Kontakt Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Rok sběru 2021 Elektronická adresa https://www.mdpi.com/2073-4344/10/7/808
Počet záznamů: 1