Počet záznamů: 1
Synthesis of new cobalt aluminophosphate framework by opening a cobalt methylphosphonate layered material
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SYSNO ASEP 0482887 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Synthesis of new cobalt aluminophosphate framework by opening a cobalt methylphosphonate layered material Tvůrce(i) Zaarour, M. (FR)
Pérez, O. (FR)
Boullay, P. (FR)
Martens, J. (DE)
Mihailova, B. (DE)
Karaghiosoff, K. (DE)
Palatinus, Lukáš (FZU-D) RID, ORCID
Mintova, S. (FR)Celkový počet autorů 8 Zdroj.dok. CrystEngComm. - : Royal Society of Chemistry - ISSN 1466-8033
Roč. 19, č. 34 (2017), s. 5100-5105Poč.str. 6 s. Forma vydání Online - E Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova cobalt aluminophosphate ; cobalt methylphosphonate ; layered materials ; crystallic structure ; X-ray diffraction Vědní obor RIV BM - Fyzika pevných látek a magnetismus Obor OECD Condensed matter physics (including formerly solid state physics, supercond.) Institucionální podpora FZU-D - RVO:68378271 UT WOS 000409204400017 EID SCOPUS 85028758072 DOI https://doi.org/10.1039/c7ce01129f Anotace A highly stable, cobalt rich, template free Co–AlPO material was prepared by opening the structure of cobalt methylphosphonate layered material under hydrothermal treatment in the presence of aluminium. CoMeP serves as the structure directing unit favoring the preferential formation of Al–O–P bonds, thus connecting the neighboring layers, which results in alternating Co–P and Al stacks. The new Co–AlPO material is monoclinic, and it is built of 12 membered ellipsoidal channels running along the crystallographic c-axis containing confined water molecules and another 6 membered hexagonal channels along the a-axis, where Co2+ cations are occasionally found. The formation of Al–O–P bonds was proved by FTIR, Raman spectroscopy, and single crystal X-ray diffraction. Pracoviště Fyzikální ústav Kontakt Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Rok sběru 2018
Počet záznamů: 1