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Water-based synthesis of TiO2/CeO2 composites supported on plasma-treated montmorillonite for parathion methyl degradation
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SYSNO ASEP 0474825 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Water-based synthesis of TiO2/CeO2 composites supported on plasma-treated montmorillonite for parathion methyl degradation Tvůrce(i) Henych, Jiří (UACH-T) SAI, RID, ORCID
Kormunda, M. (CZ)
Šťastný, Martin (UACH-T) SAI, RID
Janoš, P. (CZ)
Vomáčka, Petr (UACH-T) ORCID, SAI
Matoušek, J. (CZ)
Štengl, Václav (UACH-T) RID, ORCID, SAIZdroj.dok. Applied Clay Science. - : Elsevier - ISSN 0169-1317
Roč. 144, AUG (2017), s. 26-35Poč.str. 10 s. Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova Montmorillonite ; Parathion methyl ; Plasma treatment ; TiO2 /CeO2 composites Vědní obor RIV CA - Anorganická chemie Obor OECD Inorganic and nuclear chemistry CEP LM2015073 GA MŠMT - Ministerstvo školství, mládeže a tělovýchovy Institucionální podpora UACH-T - RVO:61388980 UT WOS 000403637100004 EID SCOPUS 85019017968 DOI 10.1016/j.clay.2017.05.001 Anotace The undemanding water-based synthesis was employed for the preparation of TiO2/CeO2 composites supported on Montmorillonite (MT). The prior plasma treatment of Montmorillonite led to significantly faster dispergation in water during the synthesis. The composites were used as reactive adsorbents against toxic organophosphorus pesticide parathion methyl. Efficient pillaring of the Montmorillonite layers by surface deposition of TiO2/CeO2 composites reflected in a substantially improved degradation activity towards parathion methyl in non-polar (heptane) and polar solvents (acetonitrile) investigated by HPLC/DAD. Moreover, the use of plasma treated Montmorillonite in the composites resulted in a higher degradation rate than with use of pristine MT. The formation of composites and their physicochemical properties were studied by XRD, XPS, FTIR, nitrogen physisorption, SEM and HRTEM/EDS mapping. Prior plasma treatment of the MT in a simple arrangement led to an easier formation of the composites and caused further improvement of the samples activity. Pracoviště Ústav anorganické chemie Kontakt Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Rok sběru 2018
Počet záznamů: 1