Počet záznamů: 1
Interlayer growth kinetics of a binary solid-solution based on the thermodynamic extremal principle: Application to the formation of spinel at periclase-corundum contacts
- 1.
SYSNO ASEP 0464268 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Interlayer growth kinetics of a binary solid-solution based on the thermodynamic extremal principle: Application to the formation of spinel at periclase-corundum contacts Tvůrce(i) Abart, R. (AT)
Svoboda, Jiří (UFM-A) RID, ORCID
Jeřábek, P. (CZ)
Povoden-Karadeniz, E. (AT)
Habler, G. (AT)Celkový počet autorů 5 Zdroj.dok. American Journal of Science - ISSN 0002-9599
Roč. 316, č. 4 (2016), s. 309-328Poč.str. 20 s. Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova reactive dffusion ; interface migration ; thermodynamic modeling ; spinel Vědní obor RIV BJ - Termodynamika Institucionální podpora UFM-A - RVO:68081723 UT WOS 000376538500001 EID SCOPUS 84969972590 DOI 10.2475/04.2016.01 Anotace A thermodynamic model has been developed for interlayer growth in a binary system between two phases of fixed composition producing an intermediate solid-solution phase. Thereby long-range diffusion, interface migration and generation/annihilation of vacancies at the reaction interfaces have been considered as potentially rate limiting. The coupling among these processes governs overall growth rate, position of the Kirkendall plane and the compositions of the solid-solution phase at the reaction interfaces. Model calculations illustrating the relations between the corresponding kinetic parameters and system evolution are presented. In particular, the systematics of non-equilibrium element partitioning across moving reaction interfaces is addressed. It is found that the deviation from equilibrium element partitioning at a moving reaction interface is a more sensitive monitor for the departure from local equilibrium than the deviation from parabolic growth behavior. Finally, the model is applied to interlayer growth of magnesio-aluminate spinel. Pracoviště Ústav fyziky materiálu Kontakt Yvonna Šrámková, sramkova@ipm.cz, Tel.: 532 290 485 Rok sběru 2017
Počet záznamů: 1