Počet záznamů: 1
Development of ICP-MS and ICP-OES methods for determination of gadolinium in samples related to hospital waste water treatment
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SYSNO ASEP 0459859 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Development of ICP-MS and ICP-OES methods for determination of gadolinium in samples related to hospital waste water treatment Tvůrce(i) Bendakovská, L. (CZ)
Krejčovská, A. (CZ)
Černohorský, T. (CZ)
Zelenková, Jana (UH-J) SAI, ORCID, RIDZdroj.dok. Chemical Papers. - : Springer - ISSN 0366-6352
Roč. 70, č. 9 (2016), s. 1155-1165Poč.str. 11 s. Forma vydání Tištěná - P Jazyk dok. eng - angličtina Země vyd. SK - Slovensko Klíč. slova gadolinium ; rare-earth elements ; bioaccumulation ; gadolinium anomaly ; inductively coupled plasma mass spectrometry (ICP-MS) ; inductively coupled plasma optical emission spectrometry (ICP-OES) Vědní obor RIV BK - Mechanika tekutin Institucionální podpora UH-J - RVO:67985874 UT WOS 000378599000003 EID SCOPUS 84974555659 DOI 10.1515/chempap-2016-0057 Anotace A suitable analytical method making possible the determination of Gd and other rare-earth elements in samples related to hospital waste water treatment was sought with regard to various aspects of the experiment aimed at monitoring the fate of Gd-based contrast agents in the aquatic environment. The discrepancies and pitfalls of the proposed methodology were considered, resulting in a functional experimental plan. The inductively coupled plasma mass spectrometry (ICP-MS) method was used for the determination of Gd and other rare earth elements in river and hospital waste water and algae Parachlorella kessleri cultured in laboratory experiments. The sample preparation of algae prior to analysis was optimised. The ICP-MS method was validated using a recovery study, sample blanks, reference materials, and comparison with the inductively coupled plasma optical emission spectrometry (ICP-OES) method. The ICP-MS method was confirmed as suitable for monitoring the biosorption/bioaccumulation of Gd in algae and for evaluating the Gd anomaly in hospital waste water and rivers of Eastern Bohemia. In the laboratory experiments, the bioconcentration factors were calculated (all in L kg−1) for algae cultured in inorganic Gd salt (about 1100), in waste water from a magnetic resonance workplace (2300) and in waste water from a hospital waste water treatment plant (4400). A positive Gd anomaly in waters from the river Elbe in the Eastern Bohemia region was found less pronounced in the areas unaffected than in the areas affected by waste waters from hospital. Pracoviště Ústav pro hydrodynamiku Kontakt Soňa Hnilicová, hnilicova@ih.cas.cz, Tel.: 233 109 003 Rok sběru 2017
Počet záznamů: 1