Počet záznamů: 1  

Remediation of Contaminated Soils by Thermal Desorption; Effect of Benzoyl Peroxide Addition.

  1. 1.
    SYSNO ASEP0459346
    Druh ASEPJ - Článek v odborném periodiku
    Zařazení RIVJ - Článek v odborném periodiku
    Poddruh JČlánek ve WOS
    NázevRemediation of Contaminated Soils by Thermal Desorption; Effect of Benzoyl Peroxide Addition.
    Tvůrce(i) Kaštánek, František (UCHP-M) RID, SAI, ORCID
    Topka, Pavel (UCHP-M) RID, ORCID, SAI
    Soukup, Karel (UCHP-M) RID, SAI, ORCID
    Maléterová, Ywetta (UCHP-M) RID, ORCID, SAI
    Demnerová, K. (CZ)
    Kaštánek, Petr (UCHP-M)
    Šolcová, Olga (UCHP-M) RID, ORCID, SAI
    Zdroj.dok.Journal of Cleaner Production. - : Elsevier - ISSN 0959-6526
    Roč. 125, JUL 1 (2016), s. 309-313
    Poč.str.5 s.
    Jazyk dok.eng - angličtina
    Země vyd.GB - Velká Británie
    Klíč. slovasoil ; hydrocarbons ; benzoyl peroxide
    Vědní obor RIVCI - Průmyslová chemie a chemické inženýrství
    CEPTA04020700 GA TA ČR - Technologická agentura ČR
    Institucionální podporaUCHP-M - RVO:67985858
    UT WOS000376697500026
    EID SCOPUS84964589672
    DOI10.1016/j.jclepro.2016.03.134
    AnotaceIn situ remediation of contaminated sites by thermal desorption is a widely accepted technology that provides a permanent solution at an economically competitive cost. In this paper, thermal desorption of various model contaminants was tested at the bench scale. Polyaromatic hydrocarbons (benzene/ toluene/xylene) and non-polar extractable compounds were selected as representatives. The electrically heated static oven worked up to 380°C with temperature gradient 6°C /min, under air flow (0.6 m3/h). Prior to an experiment, model contaminants (xylene, 2-methylnaphtalene or motor oil) were mixed with18 kg of model soil in concentrations 2-10 g/kg. The desorption process was performed with and without addition of 1 wt. % of benzoyl peroxide as an oxidant. The aim of the oxidant addition was to facilitate the chemical catalytic decomposition and/or biodegradation of desorbed organics from the soil as an alternative to usually employed incineration. In the course of the desorption process, part of the organic contaminants was oxygenated and liquids obtained after condensation of the desorbed contaminant vapours were subsequently treated by biodegradation. The application of benzoyl peroxide significantly accelerated biodegradation of organic compounds present in the condensates by Pseudomonas sp. Moreover, it was shown that the presence of partial oxidation products in the condensates did not increase their eco-toxicity.
    PracovištěÚstav chemických procesů
    KontaktEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Rok sběru2017
Počet záznamů: 1  

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