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The efficiency of micro-Raman spectroscopy in the analysis of complicated mixtures in modern paints: Munch's and Kupka's paintings under study
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SYSNO ASEP 0458227 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název The efficiency of micro-Raman spectroscopy in the analysis of complicated mixtures in modern paints: Munch's and Kupka's paintings under study Tvůrce(i) Košařová, V. (CZ)
Hradil, David (UACH-T) RID, SAI
Hradilová, J. (CZ)
Čermáková, Zdeňka (UACH-T) SAI
Němec, I. (CZ)
Schreiner, M. (DE)Zdroj.dok. Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy. - : Elsevier - ISSN 1386-1425
Roč. 156, MAR (2016), s. 36-46Poč.str. 11 s. Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova Micro-Raman spectroscopy ; Portable Raman spectrometry ; Modern paints Vědní obor RIV CA - Anorganická chemie Institucionální podpora UACH-T - RVO:61388980 UT WOS 000369201200006 EID SCOPUS 84948674078 DOI 10.1016/j.saa.2015.11.027 Anotace Twenty one mock-up samples containing inorganic pigments primarily used at the turn of the 19th and 20th century were selected for comparative study and measured by micro-Raman and portable Raman spectrometers. They included pure grounds (chalk-based, earth-based and lithopone-based), grounds covered by resin-based varnish, and different paint layers containing mixtures of white, yellow, orange, red, green, blue and black pigments, usually in combination with white pigments (titanium, zinc and barium whites or chalk). In addition, ten micro-samples obtained from seven paintings of two world-famous modern painters Edvard Munch and Frantisek Kupka have been investigated. Infrared reflection spectroscopy (FTIR), portable X-ray fluorescence (XRF) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) were used as supplementary methods. The measurements showed that blue pigments (ultramarine, Prussian blue and azurite), vermilion and ivory black in mixture with whites provided characteristic Raman spectra, while Co-, Cd- and Cr- pigments' bands were suppressed by fluorescence. The best success rate of micro-Raman spectroscopy has been achieved using the 780 nm excitation, however, the sensitivity of this excitation laser in a portable Raman instrument significantly decreased. The analyses of micro-samples of paintings by E. Munch and F. Kupka showed that micro-Raman spectroscopy identified pigments which would remain unidentified if analyzed only by SEM-EDS (zinc yellow, Prussian blue). On the other hand, chromium oxide green and ultramarine were not detected together in a sample due to overlap of their main bands. In those cases, it is always necessary to complement Raman analysis with other analytical methods. Pracoviště Ústav anorganické chemie Kontakt Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Rok sběru 2017
Počet záznamů: 1