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A new copper(II) Schiff base complex containing asymmetrical tetradentate N.sub.2./sub.O.sub.2./sub. Schiff base ligand: Synthesis, characterization, crystal structure and DFT study
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SYSNO ASEP 0448378 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název A new copper(II) Schiff base complex containing asymmetrical tetradentate N2O2 Schiff base ligand: Synthesis, characterization, crystal structure and DFT study Tvůrce(i) Grivani, G. (IR)
Baghan, S.H. (IR)
Vakili, M. (IR)
Khalaji, A.D. (IR)
Tahmasebi, V. (IR)
Eigner, Václav (FZU-D) RID, ORCID
Dušek, Michal (FZU-D) RID, ORCID, SAIZdroj.dok. Journal of Molecular Structure. - : Elsevier - ISSN 0022-2860
Roč. 1082, Feb (2015), 91-96Poč.str. 6 s. Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova Schiff-base ; copper (II) ; complex ; single-crystal ; thermal decomposition ; DFT Vědní obor RIV BM - Fyzika pevných látek a magnetismus CEP GA14-03276S GA ČR - Grantová agentura ČR Institucionální podpora FZU-D - RVO:68378271 UT WOS 000347591100011 EID SCOPUS 84911926108 DOI 10.1016/j.molstruc.2014.10.058 Anotace A new copper (II) Schiff base complex, CuL1, was prepared from the reaction of asymmetrical Schiff base ligand of L1 and Cu(OAC)2 (L1 = salicylidene imino-ethylimino-pentan-2-one). The Schiff base ligand, L1, and its copper (II) complex, CuL1, have been characterized by elemental analysis (CHN) and FT-IR and UV–vis spectroscopy. In addition, 1H NMR was employed for characterization of the ligand. Thermogrametric analysis of the CuL1 reveals its thermal stability and its decomposition pattern shows that it is finally decomposed to the copper oxide (CuO). The crystal structure of CuL1 was determined by the single crystal X-ray analysis. The CuL1 complex crystallizes in the monoclinic system, with space group P21/n and distorted square planar coordination around the metal ion. Pracoviště Fyzikální ústav Kontakt Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Rok sběru 2016
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